Chemical Storage
General Considerations for Chemical Storage Locations
- Avoid storing materials on top of cabinets. Clearance from the ceiling must be 18 inches for sprinklered labs and 24 inches for not sprinklered.
- Chemicals should be readily accessible and to reduce accidents, materials should not be stored on shelves higher than 5 feet (~1.5m).
- Ensure container weight does not exceed the load rating of the shelves. Heavier items and larger containers should be stored on lower shelves.
- Wall mounted shelving is not recommended for chemical storage.
- Corrosive liquids and Particularly Hazardous Substances (PHS) shall be stored below eye level.
- Do not store chemicals in fume hoods.
- Provide adequate storage space for chemicals within your lab.
- Keep chemicals away from sources of heat or direct sunlight.
- Use secondary containment when possible.
- Use properly rated and labeled refrigerators and freezers when storing flammable materials.
Basic chemical segregation
Corrosives-acids
- Storage: Separate acid storage cabinet
- Examples: Mineral acids, hydrochloric acid, sulfuric acid, nitric acid, perchloric acid and chromic acid
- Incompatibilities: Flammable liquids, oxidizers, poisons and bases
Corrosives-bases
- Storage: Separate corrosive storage cabinet
- Examples: Ammonium hydroxide and sodium hydroxide
- Incompatibilities: Flammable liquids, oxidizers, poisons and acids
Flammable liquids
- Storage: Grounded flammable storage cabinet
- Examples: Acetone, benzene, diethyl ether, methanol, ethanol and toluene
- Incompatibilities: Acids, bases, oxidizers and poisons
Flammable solids
- Storage: Separate storage cage in dry, cool area
- Examples: Phosphorus
- Incompatibilities: Acids, bases, oxidizers and flammable liquids
General non-reactive
- Storage: General shelving, preferably behind glass doors or below eye level
- Examples: Sodium chloride and sodium bicarbonate
- Incompatibilities: Consult SDS
Oxidizers
- Storage: Separate metal storage cabinet
- Examples: Sodium hypochlorite, peroxides, perchlorates, chlorates, nitrates, bromates and superoxides
- Incompatibilities: Flammables, combustibles and reducing agents
Poisons
- Storage: Separate area that is cool and dry within unbreakable containers
- Examples: Cyanides and heavy metal compounds such as lead, cadmium and mercury
- Incompatibilities: Flammable liquids, corrosives and oxidizers
Water reactive
- Storage: Separate area that is cool and dry in water-tight cabinet
- Examples: Sodium metal, potassium metal and lithium metal
- Incompatibilities: All water-based compounds and oxidizers